Guidance

Methyl bromide: general information

Updated 27 January 2025

Overview

Methyl bromide is a colourless, nearly odourless gas at room temperature. At very high concentrations there may be a musty or fruity odour. Other names for methyl bromide include bromomethane.

Uses of methyl bromide

Methyl bromide is used as a chemical intermediate in the production of other chemicals.

The main use of methyl bromide was as a fumigant in the control of insects, weeds and rodents. It was used to fumigate buildings, soil and products such as dry foodstuffs, fruit, vegetables and tobacco during storage. In 2005 the use and sale of methyl bromide as a pesticide/fumigant in the EU was banned, apart from quarantine and shipping uses. However, in 2010 these uses were also banned because of its adverse effects on human health and the environment.

In the past, methyl bromide was also used as a refrigerant and in fire extinguishers.

How methyl bromide gets into the environment

Methyl bromide may be released into the environment from natural sources including certain plants and some wetland areas, but oceans are thought to be a major source.

Exposure to methyl bromide

While the use of methyl bromide as a fumigant is banned in the EU, people in the UK working with ships, parcels or cargo originating from outside the EU may be exposed to products which have been fumigated with methyl bromide. Additionally, exposure could occur in workplaces where it is produced or transported. However safe limits are enforced to protect the employees. Such levels are below those that are thought to cause harmful effects.

The general public may be exposed to methyl bromide by breathing in contaminated air although exposure is likely to be very low.

How exposure to methyl bromide could affect your health

Following exposure to any chemical, the adverse health effects you may encounter depend on several factors, including the amount to which you are exposed (dose), the way you are exposed, the duration of exposure, the form of the chemical and if you were exposed to any other chemicals.

Exposure to very low levels of methyl bromide in the environment would not be expected to cause adverse health effects. Please see below for information on health effects associated with higher levels of exposure.

Exposure to methyl bromide is highly irritating to the skin, eyes and airways. Irritation of the airways can cause coughing, chest tightness and burning sensation of the nose and throat. It may also cause nausea, vomiting and abdominal pain if it is inhaled.

If methyl bromide is absorbed by the body this can result in stomach upset and damage, tiredness, behaviour changes, confusion and damage to the liver and kidneys. In severe cases methyl bromide may stop proper heart function and cause a build-up of fluid on the lungs, fitting, coma, liver damage, jaundice and death. Some effects may be delayed.

If methyl bromide comes in contact with the eyes this may result in severe irritation with redness and swelling. There may be pain and some vision problems including temporary blindness.

Very high concentrations can cause burns and blistering of the skin. Methyl bromide released under pressure onto the skin can cause frostbite.

Exposure to methyl bromide for a long period of time may cause depression and vision, hearing and concentration problems.

Methyl bromide and cancer

Due to inadequate evidence in humans and limited evidence in animals, the International Agency for Research on Cancer (IARC) have stated that methyl bromide is not classifiable as to its ability to cause cancer in humans.

Pregnancy and the unborn child 

There are limited data available on the effects of exposure to methyl bromide on pregnancy and the unborn child. Therefore, is not possible to draw any definitive conclusions. Effects on the unborn child are more likely to occur if the exposure to methyl bromide causes the mother to become unwell.

What to do if you are exposed to methyl bromide

It is very unlikely that the general population will be exposed to a level of methyl bromide high enough to cause adverse health effects. However, if you have any health concerns regarding exposure to methyl bromide seek guidance from your GP or contact NHS 111.

Additional sources of information

NHS Choices - Acid and chemical burns

NHS Choices - Poisoning

Email chemcompendium@ukhsa.gov.uk if you have any questions about this guidance or enquiries@ukhsa.gov.uk if you have any other questions.

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