IHTM30184 - Payment methods: payment by IHT direct payment scheme
From 31 March 2003 an alternative means of payment is available to taxpayers called the IHT Direct Payment Scheme (DPS).
The link below will guide you through the appropriate steps when using the IHT direct payment scheme
https://www.gov.uk/paying-inheritance-tax/deceaseds-bank-account
There are separate instructions you must follow when making a repayment of tax (IHTM31667) paid using DPS.